The radiative lifetimes of C$(A'II,, v'= 0 and 3) were determined by laser-induced fluorescence to be re(0) = 18.5 f 3 and ~(3)=11.4rt:2 cs. In addition, the lifetimes of C2(d311,, u'= 0 and 1) were measured as re =106+15 ns and 105+15 ns, respectiveiy. The error is 30.
✦ LIBER ✦
Lifetime measurements of electronically excited C3(1Πu) radicals in different vibrational states
✍ Scribed by K.H. Becker; T. Tatarczyk; J. Radić-Perić
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 436 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0009-2614
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Through a double-resonance technique, the FT-IR absorptions of the lowest-lying triplet state of C3 have been observed in argon and neon matrices. The lonp-lived P 311. state is populated by an intersystem crossing from the excited A 'II" state. The difference spectra obtained with and without Cs A