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Lifetime measurements of CuBr and CuI excited states: identification of the electronic states

โœ Scribed by Y. Lefebvre; J.M. Delaval; P. Bernage; P. Niay


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
250 KB
Volume
139
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Radiative decay of the fluorescence following resonant excitation by a pulsed dye laser has been used to measure the radiative lifetimes of excited electronic states of molecular CuBr and CuI. Comparisons are made with radiative lifetimes for CuF and CuCI, and symmetries for the ( 3d94s) Cu+ excited states assigned for the heavier CuBr and CuI copper halides.


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โœ Charles W. Bauschlicher Jr.; Harry Partridge ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 600 KB

The alX+-X3II separation is estimated to be 1804-110 cm -m, which is in reasonable agreement with the recent experimental determination that the separation in a neon matrix is between 15 and 182 cm-I. Th~ calculated spectroscopic constants for the excited states confirm the experimental assignment f