Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility

✍ Scribed by Hans-Jörg Deiseroth; Shiao-Tong Kong; Hellmut Eckert; Julia Vannahme; Christof Reiner; Torsten Zaiß; Marc Schlosser

• Publisher: John Wiley and Sons
• Year: 2008
• Tongue: English
• Weight: 390 KB
• Volume: 120
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/ange.200703900

✦ Synopsis

Wiemhöfer (WWU Münster) for performing the impedance measurements. X = Cl, Br, I. recorded at a spinning speed of 14 kHz, using 4.5-ms pulses and a relaxation delay of 0.1 s. 79 Br and 127 I MAS-NMR measurements were performed with a Bruker DSX 500 NMR spectrometer operating at frequencies of 125.3 and 100.1MHz, respectively. Spectra were recorded at a spinning speed of 15 kHz, using 1-ms (2-ms) pulses and a relaxation delay of 1 s. Chemical shifts are reported relative to 1m aqueous solutions of LiCl, KBr, and KI and to 85 % H 3 PO 4 , respectively.