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Lewis Base Catalysis of the Mukaiyama Directed Aldol Reaction: 40 Years of Inspiration and Advances

✍ Scribed by Beutner, Gregory L.; Denmark, Scott E.

Book ID
120530431
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
855 KB
Volume
52
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

Tandem and two-directional asymmetric ca
Tandem and two-directional asymmetric catalysis of the Mukaiyama aldol reaction
✍ Koichi Mikami; Satoru Matsukawa; Masako Nagashima; Hiroshi Funabashi; Hajime Mor πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 257 KB

Upon addition of an excess amount of an aldehyde 3, the Mukaiyama aldol reaction of a silyl enol ether 2 proceeds in tandem and two-directional fashion by the asymmetric catalysis of a binaphthol-derived chiral titanium complex (BINOL-Ti: 1) to give the silyl enol ether 4 in 77% isolated yield in mo