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Lewis Acid Mediated Diastereoselective Allylation of Camphorpyrazolidinone Derived α-Ketoamides.

✍ Scribed by Shy-Guey Wang; Huei Ru Tsai; Kwunmin Chen

Publisher
John Wiley and Sons
Year
2004
Weight
20 KB
Volume
35
Category
Article
ISSN
0931-7597

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Indium-mediated diastereoselective allylation reactions: preparation of tert-α-hydroxy acids
✍ Jeong Ah Shin; Joo Hwan Cha; Ae Nim Pae; Kyung Il Choi; Hun Yeong Koh; Han-Young 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 202 KB

Indium-mediated allylation reactions of a-ketoimides derived from Oppolzer's sultam were accomplished in aqueous THF in good yields and excellent diastereomeric excesses. It could be a useful method for the preparation of enantiopure t-a-hydroxy acids. When the substituent of a-ketoimides was change