Lewis acid mediated claisen-type rearrangement of aryl dienyl ethers
β Scribed by Kazuhiro Maruyama; Naoshi Nagai; Yoshinori Naruta
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 209 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
In the presence of BF3.OEt 2 aryl dienyl ethers were rearranged under mild conditions to afford dienyl p enols in good yields.
Claisen rearrangement of ally1 aryl ethers has long been studied and thermall) or acid catalyzed procedures 2) have been developed to utilize versa-
π SIMILAR VOLUMES
Allyl vinyl ethers containing an acceptor function in the 2-position are useful substrates for the Lewis acid-catalyzed Claisen rearrangement. The first synthesis of acyclic 2-(1,3-oxazolin-2-yl)-substituted allyl vinyl ethers is reported. The Lewis acid catalyzed Claisen rearrangement of these ally
Lewis-Acid-Assisted "Tandem Claisen Rearrangement": Application to the Synthesis of a New Type of Macrocycle Containing Phenolic Moieties. -The synthesis of a new type of macrocycles with four phenolic hydroxyl groups (VIII) involving a new strategy for the tandem Claisen rearrangement (VII) β (VII