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Lewis Acid Mediated Asymmetric [2,3]-Sigmatropic Rearrangement of Allylic Amines. Scope and Mechanistic Investigation

โœ Scribed by Blid, Jan; Panknin, Olaf; Tuzina, Pavel; Somfai, Peter

Book ID
120412938
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
298 KB
Volume
72
Category
Article
ISSN
0022-3263

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Lewis acid mediated [2,3]-sigmatropic re
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An investigation of the Lewis acid mediated [2,3]-sigmatropic rearrangement of allylic ammonium ylides has been conducted by employing various bases and boron Lewis acids. Using BBr 3 together with the phosphazene base 6, various allylic amines could be rearranged in good yields with low to excellen

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