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Lewis Acid-Catalyzed Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates: A New Efficient Route to 2-Styrylmalonates

✍ Scribed by Alexey O. Chagarovskiy; Olga A. Ivanova; Eduard R. Rakhmankulov; Ekaterina M. Budynina; Igor V. Trushkov; Mikhail Ya. Melnikov


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
184 KB
Volume
352
Category
Article
ISSN
1615-4150

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Lewis Acid-Catalyzed [3+4] Annulation of
✍ Olga A. Ivanova; Ekaterina M. Budynina; Alexey O. Chagarovskiy; Alexey E. Kaplun 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 348 KB 👁 2 views

## Abstract A novel Lewis acid‐catalyzed [3+4] annulation of 2‐(heteroaryl)cyclopropane‐1,1‐dicarboxylates with cyclopentadiene is reported. This reaction proceeds __via__ an electrophilic attack of the Lewis acid‐activated donor‐acceptor cyclopropane onto cyclopentadiene followed by Friedel–Crafts