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Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2

✍ Scribed by Chase, Preston A.; Jurca, Titel; Stephan, Douglas W.

Book ID: 118227497
Publisher: Royal Society of Chemistry
Year: 2008
Tongue: English
Weight: 669 KB
Volume: 14
Category: Article
ISSN: 1359-7345
DOI: 10.1039/b718598g

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## Abstract This study thoroughly examines the potential energy surfaces (PESs) of two possible mechanisms for reduction of imines by B(C~6~F~5~)~3~ and H~2~. The key reaction steps of the first catalytic mechanism, which is the focus of our study, are: (i) the uptake of H~2~ by a thermally activat