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Lewis acid catalyzed ene reactions of .alpha.,.beta.-unsaturated N-acyloxazolidinones

โœ Scribed by Snider, Barry B.; Zhang, Qingwei

Book ID
127024155
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
816 KB
Volume
56
Category
Article
ISSN
0022-3263

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Lewis Acid Catalyzed Additions to Unsatu
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โœ Biermann, Ursula ;Metzger, J. O. ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons โš– 282 KB

We are presenting our results on the alkylaluminium halide catalyzed ene addition of formaldehyde to readily available unsaturated fatty compounds to give primary homoallylic alcohols. The reaction of oleic acid and 10-undecenoic acid with formaldehyde gives (E)-S(lO)-(hydroxyrneth~ yI)octadec-l0(8)