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Lewis Acid Catalysis in Heterolysis Reactions of Glycol Ether Radicals Mimicking Diol Dehydratase-Catalyzed Reactions

โœ Scribed by Miranda, Neil; Xu, Libin; Newcomb, Martin

Book ID
126254321
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
76 KB
Volume
6
Category
Article
ISSN
1523-7060

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๐Ÿ“œ SIMILAR VOLUMES

Lewis acid catalysis in micellar systems
Lewis acid catalysis in micellar systems. Sc(OTf)3-Catalyzed aqueous aldol reactions of silyl enol ethers with aldehydes in the presence of a surfactant
โœ Shลซ Kobayashi; Takeshi Wakabayashi; Satoshi Nagayama; Hidekazu Oyamada ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Scandium triflate (Sc(OTf)3)-catalyzed aldol reactions of silyl enol ethers with aldehydes were successfully carried out in micellar systems. While the reactions proceeded sluggishly in water, remarkable enhancement of the reactivity was observed in the presence of a small amount of a surfactant. In