✦ LIBER ✦

Level-to-level vibrational energy transfer studies: energy dependence and observation of product species for azulenes(S0, Evib) + CO2

✍ Scribed by John R. Barker; Michel J. Rossi; Jack R. Pladziewicz

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 578 KB
Volume: 90
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83619-1

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✦ Synopsis

V-V cncrgy trxnsfcr from a la~ugc molecule cvcltcd to vlbrahonal cnerg~cs of chemical mtcrcst has been demonstrated by detection of -1.5% yield of C02(001) due to energy transfer from azukne (&,h = 30600 cm-'). Also, the avcrage cncrgy lost per collision by azulene vas measured as a funclion ofEv,b, and the rate constant for C&(001) dcxtrvation by azulenc was dclcrmmed.