Analysis of the muon spin rotation (@R) data for the muonic ethyl radical CH,MucH, yields &hyperfine coupling constants in good agreement with the recent level-crossing resonance (LCR ) measurements. Other coupling constants are predicted and await confirmation by LCR. The role of hyperconjugation i
Level crossing resonance detection of a muonic radical in sulphur
โ Scribed by S. F. J. Cox; I. D. Reid
- Publisher
- Springer Vienna
- Year
- 1997
- Tongue
- English
- Weight
- 160 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0937-9347
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The (CH,),COMu radical forms when positive muons are stopped in pure acetone and dilute mixtures of acetone in n-hexane or water. Muonium is the precursor of the radical in dilute solution and evidently differs from hydrogen in adding readily to the carbonyl group. In micelles this addition reaction
The effect of Zeeman levels crossing in spin-correlated radical ion pairs (naphthalene)+/(hexafluorobenzene)-was monitored as the influence of an external magnetic field on the solution fluorescence under X-irradiation (MARY spectrum). The spectra obtained exhibit a line in the field, equal to tripl