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Left-Handed Helical Ribbon Intermediates in the Self-Assembly of a β-Sheet Peptide

✍ Scribed by Marini, Davide M.; Hwang, Wonmuk; Lauffenburger, Douglas A.; Zhang, Shuguang; Kamm, Roger D.


Book ID
111969387
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
394 KB
Volume
2
Category
Article
ISSN
1530-6984

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Reaction of the ligand NN'-bis(pyridin-3-yl)-1,3-benzenedicarboxamide (1) with the diphosphanedigold(I) complex [(mu-PP)(AuO2CCF3)2] occurred by displacement of the trifluoroacetate ligands by the pyridyl groups of 1, and crystallization gave the macrocyclic complex [Au2(mu-PP)(mu-1)](CF3CO2)2 (2b),