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Lead tetraacetate oxidation of (Z)- and (E)-5, 10-Secocholest-1 (10)-ENE-3β,5α−Diol 3-acetate1

✍ Scribed by Mihailo Lj. Mihailović; Natalija Kruščić; Vladimir Pavlović; Ljubinka Lorenc


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
253 KB
Volume
97
Category
Article
ISSN
0037-9646

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## Abstract (Z)‐3β‐Acetoxy‐ and (Z)‐3 α‐acetoxy‐5, 10‐__seco__‐1 (10)‐cholesten‐5‐one (**6a**) and (**7a**) were synthesized by fragmentation of 3β‐acetoxy‐5α‐cholestan‐5‐ol (**1**) and 3α‐acetoxy‐5β‐cholestan‐5‐ol (**2**), respectively, using in both cases the hypoiodite reaction (the lead tetraac