The potential use of 1-trimethylsilyloxybicyclo[n.l.O]alkanes, 2, 1 as useful synthetic intermediates has recently been demonstrated. Not only do A serve as precursors to the corresponding cyclopropanols, ,2, 2 but treatment of ,& with acid,3 base,4 or halogen5 results in the
โฆ LIBER โฆ
Lead tetra-acetate oxidation of the longifolols. Formation of cyclopropane derivatives
โ Scribed by Lhomme, J. H.; Ourisson, G.
- Book ID
- 121445862
- Publisher
- Royal Society of Chemistry
- Year
- 1967
- Weight
- 162 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-241X
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In a previous communication' we described the formation of l+acetylamines and g,N'-dialkylureas by interaction of primary amides and lead tetra-acetate in benzene or preferably in acetic acid. Evidence was presented in support of the hypothesis that the reaction proceeds initially to the appropriate