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Layered T2-, O6-, O2-, and P2-Type A 2/3 [M‘ 2+1/3 M 4+2/3 ]O 2 Bronzes, A = Li, Na; M‘ = Ni, Mg; M = Mn, Ti

✍ Scribed by Paulsen, J. M.; Donaberger, R. A.; Dahn, J. R.

Book ID
126052924
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
456 KB
Volume
12
Category
Article
ISSN
0897-4756

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Syntheses, Crystal Structures, and Prope
Syntheses, Crystal Structures, and Properties of Novel Heterooctametallic Clusters Na2M'2[M3O4(O2CEt)8]2 (M' = Fe, Cr, Mo; M3 = Mo3, MoW2, W3)
✍ Li Xu; Zhaohui Li; Huang Liu; Jinshun Huang; Qianer Zhang 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 628 KB

A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120°C to afford