Based on N-cyclohexylaminomethanediphosphonic acid (cmdpH 4 ), four new metal diphosphonate compounds with formula M 3 (cmdpH) 2 (H 2 O) 2 [Mยผ Zn(1), Co(2)] and M 2 (cmdpH 2 ) 2 (4,4 0 -bipy) 0.5 (H 2 O) [Mยผ Co(3), Mn(4)] have been obtained and structurally determined. Compounds 1 and 2 are isostruc
Layered Structures and Pillared Layered Structures
โ Scribed by Pegie Cool; Etienne F. Vansant; Georges Poncelet; Robert A. Schoonheydt
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 51 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Two novel coordination polymers with a 3D pillaredโlayer framework, [M^II^(Tdc)(4,4โฒโBpy)]__~n~__ [M = Fe (**1**), Co (**2**); Tdc = thiopheneโ2,5โdicarboxylate; 4,4โฒโBpy = 4,4โฒโbipyridine), have been hydrothermally synthesised and structurally characterised. A simultaneous reduction of
Self-assembly of Cd(NO 3 ) 2 with o-phthalic acid monopotassium salt (KHphth) in the presence of ethylenediamine (en) produced a new heterometallic coordination polymer [CdK 2 (phth) 2 (en) 0.5 (H 2 O)] n (1). Single-crystal X-ray analyses reveal that it crystallizes in a monoclinic space group P2 1