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Lattice thermodynamics for binary closed-loop equilibria: Ordinary and polymer systems

✍ Scribed by Toshiaki Hino; Stephen M. Lambert; David S. Soane; John M. Prausnitz


Publisher
American Institute of Chemical Engineers
Year
1993
Tongue
English
Weight
772 KB
Volume
39
Category
Article
ISSN
0001-1541

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Lattice thermodynamics for aqueous salt–
✍ Toshiaki Hino; John M. Prausnitz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB 👁 2 views

A lattice model is presented to compute salt-induced liquid-liquid phase separation in aqueous polymer solutions. The Gibbs energy of mixing contains an electrostatic contribution given by Pitzer's extension of the Debye-Hu ¨ckel function, and the extended Flory-Huggins theory that uses empirical fu