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Lattice Instability of Cs2HgCl4 Crystals

โœ Scribed by A. V. Kityk; Ya.I. Shchur; A. V. Zadorozhna; I. B. Trach; I. S. Girnyk; I.Yu. Martynyuk-Lototska; O. G. Vlokh

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
217 KB
Volume
211
Category
Article
ISSN
0370-1972

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โœฆ Synopsis

The lattice dynamics of Cs 2 HgCl 4 crystals and its relation to the pressure induced proper ferroelastic instability is analyzed using a rigid-ion model in the quasiharmonic approximation. Such a simple model is already sufficient to reproduce the lattice instability leading to appearance of the proper ferroelastic phase transition. It has been shown that the lattice loses its stability with respect to the transverse acoustical mode TA Z k k b, whereas the soft optical mode (B 3g symmetry at k 0) remains stable. This fact is in agreement with the phenomenological theory.

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