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Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes

✍ Scribed by Hejl, Andrew; Day, Michael W.; Grubbs, Robert H.

Book ID
120390192
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
301 KB
Volume
25
Category
Article
ISSN
0276-7333

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A "well-defined" alkylidcne complex of the type Mo(CHCMc2Ph)(N-2,6-i-Pr2C6H3)[OCMe(CF3)2] 2 has proven to be a useful initiator in catalytic olefin metathesis reactions of interest to organic chemists. A variety of related molybdenum imido alkylidene complexes can be prepared readily from a common p