Laser Stark spectroscopy of methyl cyanide in the 10-μm region: Analysis of the ν4 and ν7 bands, and the ν7, 3ν81 interaction
✍ Scribed by S.A. Rackley; R.J. Butcher; M. Römheld; S.M. Freund; T. Oka
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 986 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0022-2852
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The perpendicular hot bands n and n 4 / 2n {2 8 0 n { 8 (E-E) occurring in the region of the n 7 fundamental of CH 3 NC (1050-1250 cm 01 , cf. J. PlıB va et al., J. Mol. Spectrosc. 173, 423-430, 1995) have been analyzed. Eleven subbands of the E-E component and 10 subbands of the A 1,2 -E component
The vibration-rotation spectrum of methyl isocyanide \(\left(\mathrm{CH}_{3} \mathrm{NC}\right)\) has been recorded with the aid of a high-resolution Fourier transform spectrometer in the region \(1370151560 \mathrm{~cm}^{-1}\) containing the perpendicular band of the fundamental vibration \(v_{6}\)
To complete the analysis of the complex infrared spectra of 14 NH 3 in the 4-to 8-µm region, we assigned nearly 1200 transitions in the 3ν 2 -ν 2 , ν 2 + ν 4 -ν 2 , ν 1 -ν 2 , ν 3 -ν 2 , 2ν 4 -ν 2 , and 4ν 2 -ν 2 hot bands using the upper state energy levels determined by our previous studies at 4 a