Laser-Raman spectra and hindered rotation in the phosphonium halides

✍ Scribed by J.J. Rush; A.J. Melveger; T.C. Farrar; Tung Tsang

• Book ID: 103010411
• Publisher: Elsevier Science
• Year: 1968
• Tongue: English
• Weight: 312 KB
• Volume: 2
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(63)80034-2

✦ Synopsis

Laser-Raman spectra have been measured for PH4C1, PIQBr and PH& Intense peaks in all the halide spectra are assigned to torsional (E ) oscillations and to the internal vibrations of the PI-I-ions. Barriers to PHZ rotation are calculated and lscussed in comparison with recent spectroscopic an structu-5. % ral results.