✦ LIBER ✦
Laser photolysis studies of chloro(tetraphenylporphynato)carbonylrhodium(III) in benzene solutions. Photo-induced decarbonylation and triplet formation
✍ Scribed by Mikio Hoshino; Katsutoshi Yasufuku
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 373 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Laser phorclysu studies of chloro(tetraphenylporphynato)carbonylrhoII) in benzene solutions revealed lhat the uiplet formatioq phokGnduc6d decarbonylation, and the isomer formationwithin 20 m after lhe laser pulre only lhc rriple1 yield was round to be dcpmdent on the laser acimtion wavelengths (532 and 355 mu).
1. Illtrodoction
Natural carbonyhnetalloporphyrins such as carbonylhemoglobin have been well established to undergo fable photoG.nduced decarbonylation [l-3].