A Fourier transform microwave (FTMW) spectroscopy-based technique for measuring the rotational spectrum of vibrational excited states is demonstrated. A pulsed infrared laser is used to prepare the excited state outside the FTMW cavity. Following laser excitation, the molecules drift into the FTMW c
β¦ LIBER β¦
Laser-microwave double and triple resonance for microwave spectroscopy of vibrationally excited molecules
β Scribed by Takami, M.; Shimoda, K.
- Book ID
- 119793037
- Publisher
- IEEE
- Year
- 1974
- Tongue
- English
- Weight
- 180 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0018-9197
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Two (A/, AK) = (2. -I)-lype vibralionally induced romlionnl transitions in Ihe us state 01 CDF, have been observed by CO2 laser-microwave double resonance. The observed microwave frequencies. combined with rhe available spoxroscopic dam. yield C, = 5673.214@5) MHz and D,, = 4.4(15) kHr.