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Laser-irradiation-induced surface graft polymerization method

✍ Scribed by Noboru Saito; Shuzo Yamashita; Takehisa Matsuda

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
112 KB
Volume
35
Category
Article
ISSN
0887-624X

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✦ Synopsis

A laser-induced surface graft polymerization method is reported in which surface radicals generated upon laser irradiation initiated radical polymerization. The radical concentrations generated upon excimer laser irradiation under vacuum on poly-(ethylene terephthalate) film surfaces were measured using a radical scavenger, 1,1diphenyl-2-picrylhydrazyl. The density of surface radicals increased with laser fluence at low fluences but decreased at high fluences. Upon laser irradiation and subsequent treatment with gaseous N,N-dimethylacrylamide, surface graft polymerization occurred.

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