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Laser-irradiation effect on poly(vinyl alcohol) films doped with nanometer-sized CdS particles: Ablation and third-harmonic generation

✍ Scribed by Yoshio Nosaka; Kazunori Tanaka; Nobuyuki Fujii


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
633 KB
Volume
47
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Ultrasmall CdS particles, whose average size was controlled by thiols to range from 2 to 4 nm, were embedded in poly(vinyl alcohol) films. Shift of the fluorescence peak associates with the shift of the absorption threshold of the films, and the fluorescence intensity increases with the decrease in the size of CdS. Laser ablation at 308 nm was investigated by monitoring the emission spectra. Third‐harmonic generation was measured for various sizes of CdS particles, and the optical nonlinearity in the nonresonance region was found to remain almost constant in the diameter range studied. © 1993 John Wiley & Sons, Inc.