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Laser-Induced Reversible Volume Phase Transition of a Poly(N-isopropylacrylamide) Gel Explored by Raman Microspectroscopy

✍ Scribed by Tsuboi, Yasuyuki; Nishino, Masayuki; Kitamura, Noboru


Book ID
111777037
Publisher
Nature Publishing Group
Year
2008
Tongue
English
Weight
491 KB
Volume
40
Category
Article
ISSN
0032-3896

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The macroscopic volume shrinkage and swelling of poly (N-isopropylacrylamide) (PNIPA) gel induced by the compositional change in the methanol-water mixed solvent is correlated to the change in the nanoscopic free volume size and numerical concentration formed in the PNIPA gels. The free volume size