Laser-induced luminescence of multilayer structures based on polyimides and CdSe and CdSe/ZnS nanocrystals
✍ Scribed by A.A. Chistyakov; S.V. Dayneko; V.A. Kolesnikov; K.E. Mochalov; V.A. Oleinikov; M.G. Tedoradze; K.V. Zakharchenko
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 106 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1612-2011
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✦ Synopsis
Laser-induced luminescence of multilayer structures based on the solids of CdSe and CdSe/ZnS nanocrystals, different organic semiconductors and on the layers of organic semiconductors with embedded nanocrystals has been investigated. Drastic decrease of luminescence quantum yield is observed in the films of CdSe nanocrystals on organic semiconductors compared to those on optical glasses. The luminescence of the nanocrystals in the matrices of organic semiconductors and in multilayer structures is shown to be suppressed. The effects observed are explained by the transfer of photogenerated carriers from the nanocrystals to the molecules of organic semiconductors. The presence of the charge transfer is confirmed by a drastic increase in the conductivity (by 2 -4 orders of magnitude) and in photovoltaic effect at the presence of CdSe and CdSe/ZnS nanocrystals in the structures under investigation. The prospects of using the multilayer structures for development new materials for solar cells are discussed. Intensity, arb. units 80 60 40 20