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Laser-induced fluorescence of selectively excited bands located within the E band's spectral range of SO2

✍ Scribed by E. Hegazi; A. Hamdan; F. Al-Adel

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 544 KB
Volume: 221
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)87012-8

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✦ Synopsis

An attempt to investigate the vibrational bands near the origin of the E band of SO* has been made in a supersonic jet experiment. Several cold vibrational bands have been identified within the 32850-32880 cm-' region and their fluorescence spectra have been selectively excited and measured. A hot band activity at * 32872 cm-' was found to persist at low rotational temperatures, which caused the Franck-Condon intensity pattern of the E band's fluorescence spectrum to vary when measured under slightly different cooling conditions. The band's upper levels were not all found to have the same vibronic symmetry as that of the E band.

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