Laser-induced fluorescence (LIF) excitation spectra of phenylcarbazole and a weakly bonded carbazole-benzene complex are presented. A prominent long progression with up to 7 quanta transitions was assigned to the intermolecular bending vibration B in the complex between the carbazole and benzene moi
β¦ LIBER β¦
Laser-induced fluorescence of jet-cooled complexes of carbazole and N-ethyl carbazole with alkyl cyanides
β Scribed by A.G. Taylor; A.C. Jones; A.R. Auty; D. Phillips
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 458 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Fluorescence excitation spectra of complexes of carbazole and N-ethyl carbazole with a series of six alkyl cyanides, in a supersonic jet, are presented. The former chromophore undergoes hydrogen bonding with these ligands; Nethylation of the chromophore prevents hydrogen bonding, but formation of complexes apparently similar in terms of both intermolecular interaction strength and geometry is observed.
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