## kr-induced fluoresr~nce excitation spectra in the z--ts phase hate been obtained for CC12 and CFCI r~diczds. The observed spacings in the excitation spectra reported here ngrec well with previous absorption ~orlr in the m3tri\.
Laser induced fluorescence of CFCl and CCl2 in the gas phase
โ Scribed by R.E. Huie; N.J.T. Long; B.A. Thrush
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 317 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The fluorescence of CFCl and CC12 excited by a tunable dye laser has been observed in the gas phase. The radiative lifetimes are 644 f 18 and 3810 i 300 ns respectively consistent with matrix results. The quenching rate ofCCl2 is greater than for CpCl and varies with the wavelength of excitation.
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## Ground -state NO2 raduxls are formed m <S ps wnh a quantum yield of =70% m 164 nm photolysls of low pressure mtromethane, as revealed by laser-Induced fluorescence probing. Raman shlftcd photolyzing pulses indlute the NO\* ylrld varies httle 1~1th \iavrlength, although a small yield of excited