Laser-induced fluorescence measurements of formaldehyde in a methane/air diffusion flame
β Scribed by Joel E. Harrington; Kermit C. Smyth
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 666 KB
- Volume
- 202
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Laser-induced fluorescence has been observed form the formaldehyde A' A,-jt 'A, electronic transition in a well characterized, laminar methane/air diffusion flame burning at atmospheric pressure. This represents the first optical measurement in flames of naturally occurring formaldehyde, an important intermediate in the oxidation of hydrocarbons. Both 355 nm and tunable dye laser excitation of fluorescence are demonstrated. The observed fluorescence signals are corrected for partition function effects and for estimated collisional quenching rates to obtain relative concentration profiles.
π SIMILAR VOLUMES
Visible fluorescence is produced using an argon-ion laser for excitation in sooting methane/air and methane/oxygen diffusion flames. This emission is attributed to small (two to four ring) polycyclic aromatic hydrocarbons, as suggested by previous studies. The key finding in the present investigatio
The oxidation of soot in a laminar diffusion flame has been studied experimentally by examining the characteristics of soot particles using laser light scattering. The kinetics mechanisms of oxidation by O2 and OH have been analyzed. The concentrations of OH radicals have been measured by laser-indu