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Laser-induced fluorescence detection of atmospheric NO_2 with a commercial diode laser and a supersonic expansion

✍ Scribed by Cleary, Patricia A. ;Wooldridge, Paul J. ;Cohen, Ronald C.

Book ID
115350388
Publisher
The Optical Society
Year
2002
Tongue
English
Weight
221 KB
Volume
41
Category
Article
ISSN
1559-128X

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The propargyl radical (CH,C-CH ) was produced in a pulsed supersonic jet expansion by the 193 nm excimer laser photolysis of propargyl chloride, and detected by the method of time-resolved infrared diode laser spectroscopy. A rotational temperature of 16 & 4 K was obtained in an experiment in which