Laser-fluorescence measurement of the 7LiD (X 1∑+) potential up to high vibrational quantum numbers

✍ Scribed by G. Ennen; Ch. Ottinger

• Publisher: Elsevier Science
• Year: 1975
• Tongue: English
• Weight: 465 KB
• Volume: 36
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(75)85675-2

✦ Synopsis

Shtcen new vibrational levels of 7LiD (X lrC> were found by analysis of lasersscited fluorescence spectra. They extend "p to u" = 20, corresponding to 825% of the dissociation eneqy of LiD. New rotational and vibrational constants wre derived from the dat;I and wcrc used for an RKR calculation of the 'LiD (X 'z') potential. Extra-polating this potenti Up to the dissochtion limit gjvcs agecment with the known dissociation ccerEy to ivithin 90 cm-'.