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Laser flash studies of thioindigo and indigo dyes. Evidence for a trans configuration of the triplet state

✍ Scribed by H. Görner; D. Schulte-Frohlinde


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
558 KB
Volume
66
Category
Article
ISSN
0009-2614

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The photochemistry of maleimide in aqueous solution is governed by the coexistence of up to three different triplet states, the keto triplet (lambda(max)=250, 330 nm, lambda(min)=290 nm, pK(a)=4.4+/-0.1, tau=5 micros), the deprotonated or enolate triplet (lambda(max)=360, 260 nm, lambda(min)=320 nm,