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Laser flash photolysis of UF6: The 17 μm infrared spectrum of the transient UF5 molecule

✍ Scribed by K.C. Kim; R. Fleming; D. Seitz; M. Reisfeld


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
280 KB
Volume
62
Category
Article
ISSN
0009-2614

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✦ Synopsis


UF5 molecules were produced from laser photolysis of very 101% pressure samples of UFh in a long path cell. The pxtlai infmed absorprion spectrum of the initially formed UFS molecule was recorded in the 17 pm region. The elrent of internd vibrational excitation of the formed molecule and its lifetime are discussed from anai_vsis of the absorption decay curve and the measured spectral contour.


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The infrared absorption spectrum of the
✍ K.C. Kim; R. Fleming; D. Seitz 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 370 KB

The infrared absorption spectrum in the 16-17 pm region of the transient UFS mofecutc formed from laser photol~s~s of UF6 is presented. The absorption contour and the intensity measurements allow tentatire assignment of the molecular structure. In a previous paper Elf we have reported a partial inf