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Laser Flash Photolysis of tert -Butyl Aroylperbenzoates: Kinetics of the Singlet and Triplet States and the Aroylphenyl Radicals 1

✍ Scribed by Shah, Bipin K.; Neckers, Douglas C.

Book ID
127150223
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
146 KB
Volume
126
Category
Article
ISSN
0002-7863

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The photochemistry of maleimide in aqueous solution is governed by the coexistence of up to three different triplet states, the keto triplet (lambda(max)=250, 330 nm, lambda(min)=290 nm, pK(a)=4.4+/-0.1, tau=5 micros), the deprotonated or enolate triplet (lambda(max)=360, 260 nm, lambda(min)=320 nm,