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Laser desorption/ionization techniques in the characterization of high-molecular-weight oil fractions—Part 2: de-asphalted oils

✍ Scribed by Andrea Rizzi; Paola Cosmina; Cristina Flego; Luciano Montanari; Anna Smaniotto; Roberta Seraglia; Pietro Traldi


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
494 KB
Volume
42
Category
Article
ISSN
1076-5174

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✦ Synopsis


Abstract

The composition of the de‐asphalted oil fraction obtained from two different Italian fields was studied by laser desorption/ionization mass spectrometry. These fractions were treated with different solvent mixtures, and subfractions containing saturates, aromatic and polar compounds were obtained and analyzed by the same instrumental approach.

The investigation showed clear differences between the samples coming from the two oils. The instrumental approach did not lead to an accurate description of the different components in terms of elemental composition and structures; however, valid information could be obtained on the molecular weight distribution of the components of the different fractions. Copyright © 2007 John Wiley & Sons, Ltd.


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Laser desorption/ionization techniques i
✍ Andrea Rizzi; Paola Cosmina; Cristina Flego; Luciano Montanari; Roberta Seraglia 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 604 KB

## Abstract The molecular weight distribution of the asphaltene fractions of two types of crude oils from two different Italian fields (samples 1 and 2) was investigated. The analytical tools used to perform these analyses were matrix assisted laser desorption ionization (MALDI) and laser desorptio