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Large temperature and solvent effects in the conformational equilibrium of phencyclidine [1-phenyl-1-(N-piperidyl) cyclohexane]

โœ Scribed by Muthiah Manoharan; Ernest L. Eliel; William R. Kenan Jr.; F.Ivy Carroll

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
267 KB
Volume
24
Category
Article
ISSN
0040-4039

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Conformation, in solution, of c-4-t-buty
Conformation, in solution, of c-4-t-butyl-1-phenyl-r-1-(N-piperidyl)cyclohexane hydrochloride. The conformational energy of t-butyl
โœ Muthiah Manoharan; Ernest L. Eliel ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 137 KB

Although the hydrochloride of c-4-t-butyl-l-phenyl-c-l-(N-piperidyl)cyclohexane crystallizes in the conformation with axial-t-butyl, it exists as an almost equimolar mixture of the two chair conformers in CD-Cl\_ solution. -The nosition of eauilibrium allows one to calculate AG:-Bu as -4.9 kcal/mol.