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Large-Scale Synthesis and Resolution of TRISPHAT [Tris(tetrachlorobenzenediolato) Phosphate(V)] Anion

✍ Scribed by Favarger, France; Goujon-Ginglinger, Catherine; Monchaud, David; Lacour, Jérôme


Book ID
126849990
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
99 KB
Volume
69
Category
Article
ISSN
0022-3263

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Synthesis and Resolution of the Configur
✍ Dr. Jérǒ;me Lacour; Catherine Ginglinger; Chantal Grivet; Dr. Gérald Bernardinel 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 412 KB

see Eq. (a)] were studied. The change in the thermodynamic stability in going from R = H to R = F (6/7 -+ 8/9) was as expected. While 7 (R = H) is 13.5 kcalmol-' less stable than 6, complex 9 (R = F ) is 17.6 kcalmol-' more stable than 8. These trends will be of use in designing appropriate ligands