LARGE SALT EFFECTS IN NON-POLAR SOLVENTS
β Scribed by Winstein, S.; Smith, S.; Darwish, D.
- Book ID
- 127341668
- Publisher
- American Chemical Society
- Year
- 1959
- Tongue
- English
- Weight
- 258 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Fast radiationless deactivation Se -+ S,-, of a photoexcited state through a "funnel" is discussed. Thz experimental rates of such transitions cannot be ehplained in general by a one-dimensional model considem only the an&e of isomerizatIon. Inclusion of the full number of degrees of freedom Ia& \*-
We study the solvent effects on the isomerization of 1,2-dichloroethane in acetonitrile, chloromethane and carbon tetrachloride by molecular dynamics simulation. The stabilization of the gauche conformer in polar solvents is found to be accompanied by a decrease in the (transition state) isomerizati