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Large Distinct Diffusivity in Binary Mixtures Confined to Zeolite NaY

✍ Scribed by Kamala, C. R.; Ayappa, K. G.; Yashonath, S.

Book ID: 127038852
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 198 KB
Volume: 109
Category: Article
ISSN: 0022-3654
DOI: 10.1021/jp0548321

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Diffusion coefficients D 1 and D 2 of a binary mixture of adsorbates of diameters 0-1 and 0-2 in the restricted regions of zeolite NaY have been obtained from molecular dynamics simulations. The results suggest that the ratio of the diffusion coefficients ff = D1/D 2 exhibit unusual behaviour with a