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Lanthanide Triflates-Mediated Emulsion Cationic Polymerization of p -Alkoxystyrenes in Aqueous Media 1

✍ Scribed by Satoh, Kotaro; Kamigaito, Masami; Sawamoto, Mitsuo

Book ID
121868428
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
294 KB
Volume
33
Category
Article
ISSN
0024-9297

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The synthesis of poly(methylhydrogeno)siloxane (PMHS) by cationic polymerization of 1,3,5,7-tetramethylcyclotetrasiloxane was studied in aqueous emulsion using dodecylbenzene-(D 4 H) sulphonic acid (DBSA) as emulsiΓΌer/initiator. With pure DBSA, the rates of polymerization are very high and the PMHS