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Lanthanide shift reagents. X-ray structure of the eight-coordinate bis(4-picoline) adduct of 2,2,6,6-tetramethylheptane-3,5-dionatoholmium, Ho(dpm)3(4-pic)2

✍ Scribed by Horrocks, William DeW.; Sipe, James P.; Luber, Joseph R.


Book ID
126989773
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
396 KB
Volume
93
Category
Article
ISSN
0002-7863

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The 2,3-epoxide, a donor in lanthanide s
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Lanthanide-induced shifts in the 'H-n.m.r. spectra of the methyl 2,3-anhydro-4,6-0-benzylidene-D-hexopyranosides [manno (1 and 5), allo (2 and 6), gulo (3 and 7), Q! and 0, respectively, and wtalo (4)] have been measured. The observed shift data for the cx-manno, @-allo, and fl-gulo epoxides were i