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Lanthanide shift reagent effects on NMR spectra of organosulfur compounds-HSAB theory

✍ Scribed by Terence C. Morrill; Robert J. Opitz; Richard Mozzer


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
269 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis


Because of the tremendous value of lanthanide shift reagents for simplification of NMR spectra of organic compounds, it is especially important to know the precise structural features that mark an organic substrate as amenable to shift reaqent analysis. Despite the large . amount of published work on shift reaqents', surprisingly little work has been done to identify the microscopic details and theoretical basis for identification of substrates that will interact with shift reaqents to a degree sufficient for analysis. The results of the work in our 76, * d.

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