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Lanthanide-Organic Frameworks Based on {Ln4(μ3-OH)4(μ2-OH)2} Cluster Units

✍ Scribed by Wei-Hui Fang; Zhi-Long Wang; Guo-Yu Yang

Book ID
106406539
Publisher
Springer
Year
2010
Tongue
English
Weight
417 KB
Volume
21
Category
Article
ISSN
1040-7278

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✍ Ling-Ling Zheng; Hao-Xiang Li; Ji-Dong Leng; Jing Wang; Ming-Liang Tong 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 534 KB

## Abstract Hydrothermal reactions of CdCl~2~·2.5H~2~O or ZnCl~2~, sodium dicyanamide, and sodium azide yield two interesting photoluminescent coordination polymers, namely, [Cd{Cd~3~(μ~3~‐OH)(dcadtzH)~3~(H~2~O)~6~}~2~] (1) and [Zn~5~(μ~3~‐OH)~2~(μ‐OH)~2~(dcadtz)~2~]·2H~2~O (2) [dcadtzH~3~ = bis(5‐