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Lanthanide Metallocene Complexes of the 1,3,4,6,7,8-Hexahydro-2 H -pyrimido[1,2- a ]pyrimidinato Ligand, (hpp) 1−

✍ Scribed by Evans, William J.; Montalvo, Elizabeth; Dixon, Dustin J.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.


Book ID
118208850
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
220 KB
Volume
47
Category
Article
ISSN
0020-1669

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## Abstract The 6‐(3‐hydroxypropylamino)‐3‐methylpyrimidine‐2,4‐dione (1) did not afford the expected 6‐(3‐chloro‐propylamino)‐ derivative on reaction with thionyl chloride, but, instead, the pyrimidine rings were joined __via__ a sulfur bridge to give 9,9′‐thiobis(1,2,3,4,7,8‐hexahydro‐7‐melnyl‐6_