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Lanthanide induced intramolecular coupling of aldehydes and ketones with electron-deficient olefins

✍ Scribed by Eric J. Enholm; Antigone Trivellas


Book ID
104232802
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
243 KB
Volume
30
Category
Article
ISSN
0040-4039

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Gas-phase chemistry of electron deficien
✍ I. K. Gregor πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 432 KB

Reactions in the gas phase of the 13-and lklectron radical anions [Cr(CO),]-' and [Cr(CO),]-\* with a series of 27 aldehydes, ketones, esters and ethers have been examined. Sequential alkane eliminations and metal-bonded CO ligand displacements were the principal reactions identified for the RCHO/[C