The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model
✦ LIBER ✦
Ladder operators in commutator perturbation method
✍ Scribed by Adelio Matamala-Vásquez
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 195 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0020-7608
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✦ Synopsis
The present work is a version of Van Vleck᎐Primas perturbation method in terms of generalized ladder operators. Using the superoperator approach, a fully general, self-consistent and a totally free scheme from representation is developed.
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